Homogeneous hydrogenations ofα, β-unsaturated compounds using pentacyanocobaltate (II) anion as catalyst system
نویسندگان
چکیده
منابع مشابه
A computational experiment to study hydrogenations of various unsaturated compounds catalyzed by a rationally designed metal-free catalyst.
Metal-free hydrogenation has been proposed to be a green alternative to the conventional hydrogenation mediated by precious transition metal complexes. Thanks to the discovery of FLP (frustrated Lewis pair) chemistry, the field has recently witnessed significant progress. Inspired by the FLP idea of synergically utilizing the catalytic effects of Lewis acid and base, we previously proposed a st...
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Alkylation reactions of the nucleoside guanosine (Guo) by the α,β-unsaturated compounds (α,β-UC) acrylonitrile (AN), acrylamide (AM), acrylic acid (AA) and acrolein (AC), which can act as alkylating agents of DNA, were investigated kinetically. The following conclusions were drawn: i) The Guo alkylation mechanism by AC is different from those brought about the other α,β-UC; ii) for the first th...
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ژورنال
عنوان ژورنال: Proceedings of the Indian Academy of Sciences - Section A
سال: 1977
ISSN: 0370-0089
DOI: 10.1007/bf03046875